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101.
Zhuliang Zhong Donghui Ma Gaoyuan Zhao Huilin Li Dengyu Xu Dr. Xingang Xie Prof. Dr. Xuegong She 《化学:亚洲杂志》2015,10(12):2599-2603
The first asymmetric total synthesis of kravanhin B has been accomplished with a linear reaction sequence of 13 steps starting from (R)‐(?)‐carvone. The synthesis features an intramolecular aldol cyclization to construct the desired cis‐fused decalin skeleton and an acid‐catalyzed dehydration and olefin isomerization to install the γ‐butenolide ring. 相似文献
102.
Kun Xu Xiuling Li Pengzuo Chen Dan Zhou Changzheng Wu Yuqiao Guo Lidong Zhang Jiyin Zhao Xiaojun Wu Yi Xie 《Chemical science》2015,6(1):283-287
Ferromagnetic two-dimensional (2D) ultrathin nanosheets hold great promise for next generation electronics. Ferromagnetic metal-free materials that usually possess only an s/p electronic configuration with weak spin–orbit coupling and a large spin relaxation time, would play an important role in constructing future spintronic devices. However, the absence of an intrinsic spin ordering structure in most metal-free materials greatly hampers the widening scope of ferromagnetic 2D nanostructures as well as in-depth understanding of their ferromagnetic nature. Herein, the induction of intrinsic ferromagnetism in 2D metal-free g-C3N4 ultrathin nanosheets has been achieved through a new effective strategy whereby hydrogen dangling bonds are introduced. In our case, g-C3N4 ultrathin nanosheets with hydrogen dangling bonds showed obvious room temperature ferromagnetic behavior that could even be tuned by the concentration of hydrogen. This work will pave a new pathway to engineer the properties of 2D nanomaterial systems. 相似文献
103.
Xiangrui Yang Shichao Wu Yang Li Yu Huang Jinyan Lin Di Chang Shefang Ye Liya Xie Yuan Jiang Zhenqing Hou 《Chemical science》2015,6(3):1650-1654
Delicate mesoscopic architectures, bearing complex forms with multiple hierarchy levels, lead to significant functions in biogenic minerals. Herein, a bio-inspired approach was developed to fabricate comet-shaped assemblies of an anti-tumor drug – 10-hydroxycamptothecin (HCPT). The anti-solvent co-precipitation of HCPT and the excipient – PEG-b-PLGA – within the emulsifier leads to the immediate nucleation of comet bundles, followed by a secondary nucleation to generate the comet head, which is an assembly of nanofibers aligned almost in parallel. The continuous manufacturing furnishes drug–excipient hybrid particles with high drug-loading and a sustained drug release profile. This simple and efficient bio-inspired approach led to a promising sustained local drug delivery system, and could be extended to the fabrication of other functional organic materials bearing mesoscopic structural units. 相似文献
104.
Yuantong Liang Chenguang Lu Defang Ding Man Zhao Dawei Wang Chao Hu Jieshan Qiu Gang Xie Zhiyong Tang 《Chemical science》2015,6(7):4103-4108
Graphene quantum dots (GQDs) are shown to serve as phase transfer agents to transfer various types of nanoparticles (NPs) from non-polar to polar solvents. Thorough characterization of the NPs proves complete native ligand exchange. Pellets of this GQD–NP composite show that the GQDs limit the crystal size during spark plasma sintering, yielding enhanced thermoelectric performance compared with NPs exchanged with inorganic ions. A photoluminescence study of the GQD–NP composite also suggests energy transfer from GQDs to NPs. 相似文献
105.
106.
Xiao Shi Yongjun Li Ali Emrouznejad Jianhui Xie Liang Liang 《The Journal of the Operational Research Society》2017,68(9):1045-1055
This paper develops a novel two-stage cost efficiency model to estimate and decompose the potential gains from Mergers and Acquisitions (M&As). In this model, a hypothetical DMU is defined as a combination of two or more candidate DMUs. The hypothetical DMU would surpass the traditional Production Possibility Set (PPS). In order to solve the problem, a Merger Production Possibility Set (PPSM) is constructed. The model minimizes the total cost of the hypothetical DMU while maintaining its outputs at the current level, and estimates the overall merger efficiency by comparing its minimal total cost with its actual cost. Moreover, the overall merger efficiency could be decomposed into technical efficiency, harmony efficiency, and scale efficiency. We show that the model can be extended to a two-stage structure and these efficiencies can be decomposed to both sub-systems. To show the usefulness of the proposed approach, we applied it to a real dataset of top 20 most competitive Chinese City Commercial Banks (CCBs). We concluded that (1) there exist considerably potential gains for the proposed merged banks. (2) It is also shown that the main impact on potential merger gains are from technical and harmony efficiency. (3) As an interesting result we found that the scale effect works against the merger, indicating that it is not favorable for a full-scale merger. 相似文献
107.
Ya-sheng Huang Qi-qi Yu Yin Chen Min-jie Cheng Li-ping Xie 《Chemistry Central journal》2017,11(1):120
Background
The plant Alisma plantago-aquatica Linnaeus, which is widely distributed in southwest of China, is the main material of traditional Chinese medicine “Zexie”. It was used as folk medicine for immune-modulation, anti-tumor, anti-inflammatory and antibacterial. Previous chemical studies on A. plantago-aquatica reported the identification of triterpenes, diterpenes, sesquiterpenes, steroids, alkaloids and phenolic acid. Terpenes and phenolic acid were regard as major secondary metabolites from this medicine plant.Results
A new phenolic acid, plantain A (1), along with four known compounds (2–5) were isolated and identified from A. plantago-aquatica by extensive chromatographic and spectrometric methods. In the present study, the levels of TNF-α, IL-1β, COX-2, PEG2 and TGF-β1 were increased in model group rats, whereas on treatment with the isolated compound (1 and 4) at 50 mg/kg, there was a significant decrease in the cytokine levels. Therefore, the anti-CNP effect of 1 and 4 may be related to their anti-inflammatory properties.Conclusions
A new phenolic acid and four known phenolic compounds were isolated from A. plantago-aquatica. Moreover, compounds 1 and 4 shows significant anti-chronic prostatitis activity in rats.108.
Dr. Hao Wang Dr. Jiji Zhang Prof. Dr. Zuowei Xie 《Angewandte Chemie (International ed. in English)》2017,56(31):9198-9201
A fully reversible photothermal isomerization between carborane-fused trigonal-planar azaborole (dark-purple) and tetrahedral borirane (pale-yellow) has been observed, leading to the isolation and structural characterization of the first example of carborane-fused borirane. DFT calculations indicate that the azaborole is thermodynamically more stable than the borirane by 11.2 kcal mol−1, and the energy barrier for the thermal conversion from azaborole to borirane is 35.5 kcal mol−1. The reactivity studies show that the B−C(cage) bond in borirane can be broken in the reaction with CuCl, HCl, or elemental sulfur. 相似文献
109.
We prove the existence of a weak solution for a generalized quantum MHD equation in a 2-dimensional periodic box for large initial data. The existence of a global weak solution is established through a three-level approximation,energy estimates, and weak convergence for the adiabatic exponent γ 1. 相似文献
110.
In this paper, we will use the Schwarz lemma at the boundary to character the distortion theorems of determinant at the extreme points and distortion theorems of matrix on the complex tangent space at the extreme points for normalized locally biholomorphic quasi-convex mappings in the unit ball B n respectively. 相似文献